The Periodic Table: Its Story and Its Significance

The Periodic Table: Its Story and Its Significance
by Eric R. Scerri

The Periodic Table: Its Story and Its Significance
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Book Summary Information

Author: Eric R. Scerri
Edition: Hardcover
Audio: English (Unknown); English (Original Language); English (Published)
Published: 2006-09-15
ISBN: 0195305736
Number of pages: 368
Publisher: Oxford University Press, USA

Book Reviews of The Periodic Table: Its Story and Its Significance

Book Review: A book that honors "one of the most powerful icons in science"
Summary: 5 Stars

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"In spite of the central...role of the periodic table [of the elements], very few authors have felt drawn to write books on its evolution. There is no book that deals adequately with the historical, and especially the conceptual, aspects of the periodic system [that holds that there is a fundamental relationship among the elements] or its significance in chemistry and science generally. It is with the aim of injecting a more philosophical treatment to understanding the periodic system that [this book] has been undertaken...this book is not intended as a work of historical scholarship...the reader is [taken] on an interdisciplinary tour of the many areas of science that are connected with the periodic system, including physics, mathematics, computational methods, history and philosophy of science, and of course, chemistry."

The above is found in the introduction to this fascinating, extremely well researched book by Dr. Eric Scerri, a professor of chemistry and history & philosophy of science at UCLA. This book is fittingly dedicated to the 100TH anniversary of the death of Dimitri Mendeleev (1834 to 1907).

The periodic table of the elements--what is it? Simply, it is basically a two-dimensional representation of a periodic system (that is explained above). The aim of this book is to bring the story of the periodic table "up to date."

This book from my own personal perspective can roughly be divided into five parts:

(I) An overview of the periodic system. (1 chapter)
(II) The development of the periodic table. (4 chapters)
(III) The nucleus and the periodic table: radioactivity, atomic number (the number of protons contained in the nucleus of the atom of an element), and isotopy (isotopes are any of two or more forms of an element having the same number of protons but differing in the number of neutrons). (1 chapter)
(IV) Electronic explanations for the elements of the periodic table: physics versus chemistry. (3 chapters)
(V) Astrophysics, element formation, other chemical trends that defy neat explanations, and three fundamental questions regarding the periodic table. (1 chapter)

One of the key features of this book, as mentioned above, is that it is well researched. However, Scerri goes one step beyond mere information gathering. He actually questions the information he has found. Here are just three examples:

(1) "The notion that the periodic table was deduced from quantum theory by [physicist Niels] Bohr [as the historical record implies] is something of an exaggeration."
(2) "This, I submit, suggests remarkable foresight and intuition on the part of [chemical writer] Gmelin, as does the way in which he uses his system to ground the presentation of the chemistry of these elements. Yet Gmelin's contribution to the classification of the elements has not been sufficiently appreciated of chemistry, or even historians of the periodic system."
(3) Clearly [chemist Dimitri] Mendeleev was spectacularly successful in [his] predictions [of new elements] but perhaps not quite to the extent that is implied by the more selective tables of comparison that regularly appear in chemistry textbooks and even histories of chemistry."

Another feature of this book is the inclusion of the actual writings of key people involved in the development of the periodic table. I found all of these interesting.

Yet another feature is that it is jam-packed with charts, tables, diagrams, etc. so readers can see for themselves what is going on. Some of these tables, etc. are actual copies from historical documents. As well, there are black and white portraits of some of those who contributed to some aspect of the formation and understanding of the periodic table.

The majority of the chapters end with a conclusion that consolidates all the information in a particular chapter. I found these most helpful.

Finally, I feel that this book can be read by all who are interested in the periodic table. However, the author assumes some science background. Many terms are defined in the book's main narrative but many are not. Thus, it would have been helpful if an appendix explaining key terms was also included. As well, a glossary would have been most helpful. Of course, any difficulties can be resolved by referring to a good, standard dictionary or even a basic science dictionary (especially for part IV above).

In conclusion, there are elements of the periodic table that are named after admired others. Examples include Einsteinium and Mendelevium. Eric Scerri has written a comprehensive book that honors the periodic table. Perhaps when a new element is discovered it should be named "Scerrium."

(first published 2006; acknowledgements; introduction; 10 chapters; main narrative 285 pages; notes; index)

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Summary of The Periodic Table: Its Story and Its Significance

The periodic table is one of the most potent icons in science. It lies at the core of chemistry and embodies the most fundamental principles of the field. The one definitive text on the development of the periodic table by van Spronsen (1969), has been out of print for a considerable time. The present book provides a successor to van Spronsen, but goes further in giving an evaluation of the extent to which modern physics has, or has not, explained the periodic system. The book is written in a lively style to appeal to experts and interested lay-persons alike.

The Periodic Table begins with an overview of the importance of the periodic table and of the elements and it examines the manner in which the term 'element' has been interpreted by chemists and philosophers. The book then turns to a systematic account of the early developments that led to the classification of the elements including the work of Lavoisier, Boyle and Dalton and Cannizzaro. The precursors to the periodic system, like D�bereiner and Gmelin, are discussed. In chapter 3 the discovery of the periodic system by six independent scientists is examined in detail.

Two chapters are devoted to the discoveries of Mendeleev, the leading discoverer, including his predictions of new elements and his accommodation of already existing elements. Chapters 6 and 7 consider the impact of physics including the discoveries of radioactivity and isotopy and successive theories of the electron including Bohr's quantum theoretical approach. Chapter 8 discusses the response to the new physical theories by chemists such as Lewis and Bury who were able to draw on detailed chemical knowledge to correct some of the early electronic configurations published by Bohr and others.

Chapter 9 provides a critical analysis of the extent to which modern quantum mechanics is, or is not, able to explain the periodic system from first principles. Finally, chapter 10 considers the way that the elements evolved following the Big Bang and in the interior of stars. The book closes with an examination of further chemical aspects including lesser known trends within the periodic system such as the knight's move relationship and secondary periodicity, as well at attempts to explain such trends.

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